Manipulating nanoparticles and enhancing spectroscopy with surface plasmons

Prof. Ken Crozier

School of Engineering and Applied Sciences
Harvard University

Thursday October 08, 2009

3:00pm - 4:30 pm

500 Classroom South

Abstract:

Field enhancement from surface plasmon structures presents new opportunities for optical manipulation and surface enhanced Raman spectroscopy (SERS). We demonstrate the propulsion of gold nanoparticles using surface plasmon polaritons (NanoLetters 9, 2623 (2009)). SPPs are excited on a thin gold film. The resultant evanescent field draws nanoparticles toward the film, where they are propelled along by the optical scattering force. We describe related work on Fresnel zone plate optical tweezers. We show that these offer comparable performance to conventional optical tweezers (APL 92, 071112 (2008)), but with considerably smaller footprints. We describe our work on metal nanoparticle substrates for SERS. Arrays of metal nanoparticles are often used for SERS, but the interactions between nanoparticles are frequently overlooked. We demonstrate that periodic metal nanoparticle arrays can exhibit spectrally-narrow surface plasmon resonances, with numerical simulations predicting considerably enhanced optical near-fields (APL 93, 181108 (2008)). To conclude, we describe a novel SERS substrate consisting of a metal nanoparticle array separated from a gold film by a thin SiO2 spacer (Opt Lett 34, 244 (2009)). We show that the double plasmon resonances of these structures enable field enhancement at both pump and Stokes frequencies (FiO 2009, paper FWT5).


Biography:

Ken Crozier is John Loeb Associate Professor of the Natural Sciences at Harvard University. His work has been featured in MIT Technology Review, Newsweek and Laser Focus World. MIT Technology review highlighted optical antennas as being one of The Top 10 Emerging Technologies for 2007. He received his undergraduate degrees in Electrical Engineering and Physics at the University of Melbourne, Australia. He was awarded the L.R. East Medal (university medal in engineering) by the University of Melbourne. He received his PhD in Electrical Engineering from Stanford University in 2003 under Professors Calvin Quate and Gordon Kino. He was a recipient of an NSF CAREER award in 2008.


More information on Dr. Crozier and his research can be found on his research website: http://www.seas.harvard.edu/crozier/index.html